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The molecule cycles between the two states continuously as it works, the same redox principle that governs glutathione's own GSH and GSSG cycle, only carried out in the fatty membrane rather than the watery interior

GPX7 can transmit oxidative stress signals by forming disulfide bonds between its catalytic sites Cys57 and Cys86 residues, and this oxidized form of GPX7 can bind to each other with GRP78 and form covalent bond intermediates between Cys86 of GPX7 and Cys41/Cys420 of GRP78 (Wei et al., 2012) (Figure 5)

10.1016/j.fertnstert.2024.09.038 38 ConfortiA.IorioG

Cells 11 , 1871 (2022)

doi: 10.3164/jcbn.12-122 49 KimSHKimSHLeeJHLeeBHYoonHJShinDHet al